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Understanding the kinetics, transfers and reactions in biological gas desulphurisation process

  • 1 November, 2022
  • Wageningen University, Mathematical and Statistical Methods
  • K.J. Keesman
  • C.J.N. Buisman

Since biogas and landfill gas streams are renewable energy sources, their global use has increased during the last decades and is expected to remain rising. Typically, toxic hydrogen sulphide (H2S) needs to be removed from these gas streams to prevent harmful sulfur dioxide emissions. The biological gas desulfurisation process under haloalkaline allows for the removal of H2S and the harvesting of elemental sulfur in an environmentally friendly way.

In the biological gas desulfurisation process, gas, liquid, and solid phases co-exist. For instance, in the absorber, a gas phase (sour gas) is contacted with a liquid phase (haloalkaline solution), which contains solid phases (biosulfur particles and microorganisms). While the microbial community and its associated kinetics have been extensively studied, a number of phenomena in the biological gas desulfurisation process are not yet fully understood. The recently discovered electron shuttling capacity of sulfide oxidizing bacteria is one of these. Due to these phenomena, dissolved sulfide is removed from process solution, without consuming oxygen. Other not fully understood phenomena are, for instance, the enhancement of H2S absorption by bacteria and the sulfur crystals formation. All of these processes are hypothesized to occur at the interfaces of the biological desulfurization process. Hence, research is required to investigate the interplays between kinetics of chemical and biological reactions and transfer rates at the interfaces.

This project aims to understand the interplays between the kinetics of the biological reactions, the kinetics of the chemical reactions, and the transfer rates around the various gas-liquid and liquid-solid interfaces in the biological gas desulfurisation process. In the last decennia, a large number of projects have been executed, resulting in a vast amount of experimental data. However, a minimum amount of the full potential of the work has been utilized, since the majority has not been used for modelling to unravel the aforementioned phenomena. Hence, part of this work will be focussing on developing models describing the transfer and reaction kinetics at the interfaces. In addition, next to utilizing data obtained in previous work, experimental work will be performed to gather data for model calibration and verification.


Joris Bergman

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